Poly(vinyl acetate) (PVAc) and natural rubberblends (NR) were prepared by low shear blending of the corresponding lattices. Thin films were cast using a doctor blade technique. SEM and DMA confirmed the essential immiscibility of the two polymers. Even when the poly(vinyl acetate) forms the matrix phase, it still containsdomains encapsulated by a rubber phase where particles that resemble the original latex are visible. This incomplete droplet coalescence of the poly(vinyl acetate) is attributed to the fact that the rubber latex droplets were an order of magnitude smaller than the poly(vinyl acetate) latexdroplets. Tensile testing revealed a nonlinear dependence of tensile strength and elongation on blend composition.Surprisingly good tensile yield strengths were obtained at intermediate to high PVAc contents. Thermogravimetric analysis of degradation in air and nitrogen atmospheresindicated independent degradation of the parent polymers.
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